(Edit March 17th 2017:)
I never imagined this would get over seventy five thousand views, I initially only made it to show my friend Tendo Pain’s Voice since I personally thought Troy Baker did an excellent job.

Pain’s assault on the leaf village begins in episode 157. However, the battle between Naruto and Pain starts at episode 163; the Dialog between Naruto and Pain starts in Episode 165, 13 minutes in.

Here’s some links:

Ep 157 Assault on the Leaf Village!:
http://kissanime.ru/Anime/Naruto-Shippuuden-Dub/Episode-157-Assault-on-the-Leaf-Village?id=99178

Ep 163 Explode! Sage Mode:
http://kissanime.ru/Anime/Naruto-Shippuuden-Dub/Episode-163-Explode-Sage-Mode?id=99184

Ep 165, Nine tails, Captured!:
http://kissanime.ru/Anime/Naruto-Shippuuden-Dub/Episode-165-Nine-Tails-Captured?id=99186

The song you’ve all been wanting to know that plays is “Burial” and here’s a link because… y’know, I don’t hate you guys.

“Burial”

(Bonus Soundtracks you might like.)
“Scene of a Disaster”

“Loneliness”

“Tragic”

“Experienced Many Battles”

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